| Title | Name | Years |
|---|---|---|
| First Vicar Apostolic of Hyderabad | Archbishop Daniel Murphy | 1851-1865 |
| Second Vicar Apostolic of Hyderabad | Bishop Domenico Barbero, P.I.M.E. | 1870-1881 |
| Third Vicar Apostolic of Hyderabad & First Bishop of Hyderabad |
Bishop Pietro Caprotti, P.I.M.E. | 1882-1897 |
| Second Bishop of Hyderabad | Bishop Pietro Andrea Vigane, S.J. | 1897-1908 |
| Third Bishop of Hyderabad | Most Rev. Dennis Vismara, P.I.M.E. | 1909-1948 |
| Fourth Bishop of Hyderabad | Most Rev. Alphonsus Beretta | 1950-1953 |
| First Archbishop of Hyderabad | Most Rev. Joseph Mark Gopu | 1953-1971 |
| Second Archbishop of Hyderabad | Most Rev. Samineni Arulappa | 1972-2000 |
| Third Archbishop of Hyderabad | Most Rev. Marampudi Joji | 2000-2010 |
| Fourth Archbishop of Hyderabad | Archbishop Thumma Bala | 2011-2020 |
| Fifth Metropolitan Archbishop of Hyderabad | Cardinal Poola Anthony | 2020–till date |